Bride, Groom, Maid of Honor, Best Man, Mother of the Bride, Wedding Coordinator (if applicable).
Your schedule should include time blocks for: Bride getting ready, groom getting ready, first look (if applicable), bridal party formals, family formals, ceremony, cocktail hour, couple's photos, reception, and Bride & Groom exit.
(i.e. items you hand made, family memorabilia, sentimental items, details unique to the bride and groom's personalities, etc.)
(i.e. the groom will sing the bride a song at the alter, signing of the marriage certificate during ceremony, etc.)
(i.e: photos in front of the red barn are a must!)
(So I can recommend great honeymoon destinations to other couples, and also, so I know when not to contact you!) ;)
The more info I have about your wedding, the more prepared I can be when photographing it.